Lithium atom storage in nanoporous cellulose via surface induced Li2\rm Li_2 breakage

preprint2014arXivOpen access

Abstract

We demonstrate a physical mechanism that enhances a splitting of diatomic Li2\rm Li_2 at cellulose surfaces. The origin of this splitting is a possible surface induced diatomic excited state resonance repulsion. The atomic Li is then free to form either physical or chemical bonds with the cellulose surface and even diffuse into the cellulose layer structure. This allows for an enhanced storage capacity of atomic Li in nanoporous cellulose

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