Abstract

We report the first principle calculations of the lattice dynamics of KNi2_{2}Se2_2 together with the Raman scattering study.\ We have observed three out of four Raman active modes predicted by the factor group analysis. Calculated phonon frequencies are in good agreement with experimental findings.\ Contrary to its iron counterpart (Kx_xFe2−y_{2-y}Se2_2), K0.95_{0.95}Ni1.86_{1.86}Se2_2 does not show vacancy ordering.

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