Large-scale multiconfiguration Dirac-Hartree-Fock calculations for astrophysics: n=4 levels in P-like ions from Mn~XI to Ni~XIV

preprint2020arXivOpen access

Abstract

Using the multiconfiguration Dirac-Hartree-Fock and the relativistic configuration interaction methods, a consistent set of transition energies and radiative transition data for the lowest 546 (623, 701, 745) states of the 3p43d3p^4 3d, 3s3p23d23s 3p^2 3d^2, 3s3p34p3s 3p^3 4p, 3s3p43s 3p^4, 3s23d33s^2 3d^3, 3s23p23d3s^2 3p^2 3d, 3s23p24d3s^2 3p^2 4d, 3s23p24s3s^2 3p^2 4s, 3p33d23p^3 3d^2, 3p53p^5, 3s3p3d33s 3p 3d^3, 3s3p33d3s 3p^3 3d, 3s3p34s3s 3p^3 4s, 3s23p3d23s^2 3p 3d^2, %3s23p24f3s^2 3p^2 4f, 3s23p24p3s^2 3p^2 4p, 3s23p33s^2 3p^3 configurations in Mn~XI (Fe~XII, Co~XIII, Ni~XIV) is provided. The comparison between calculated excitation energies for the n=4n=4 states and available experimental values for Fe XII indicate that the calculations are highly accurate, with uncertainties of only a few hundred cm−1^{-1}. Lines from these states are prominent in the soft X-rays. With the present calculations, several recent new identifications are confirmed. Other identifications involving 3p24d3p^2 4d levels in Fe~XII that were found questionable are discussed and a few new assignments are recommended. As some n=4n=4 states of the other ions also show large discrepancies between experimental and calculated energies, we reassess their identification. The present study provides highly accurate atomic data for the n=4n=4 states of P-like ions of astrophysical interest, for which experimental data are scarce.

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