Is there a fractional breakdown of the Stokes-Einstein relation in Kinetically Constrained Models at low temperature?

preprint2014arXivOpen access

Abstract

We study the motion of a tracer particle injected in facilitated models which are used to model supercooled liquids in the vicinity of the glass transition. We consider the East model, FA1f model and a more general class of non-cooperative models. For East previous works had identified a fractional violation of the Stokes-Einstein relation with a decoupling between diffusion and viscosity of the form D∼τ−ξD\simτ^{-ξ} with ξ∼0.73ξ\sim 0.73. We present rigorous results proving that instead log⁡(D)=−log⁡(τ)+O(log⁡(1/q))\log(D)=-\log(τ)+O(\log(1/q)), which implies at leading order log⁡(D)/log⁡(τ)∼−1\log(D)/\log(τ)\sim -1 for very large time-scales. Our results do not exclude the possibility of SE breakdown, albeit non fractional. Indeed extended numerical simulations by other authors show the occurrence of this violation and our result suggests Dτ∼1/qαDτ\sim 1/q^α, where qq is the density of excitations. For FA1f we prove fractional Stokes Einstein in dimension 11, and D∼τ−1D\simτ^{-1} in dimension 22 and higher, confirming previous works. Our results extend to a larger class of non-cooperative models.

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