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Interplay of Magnetic Exchange Interactions and Ni-S-Ni Bond Angles in Polynuclear Nickel(II) Complexes

The ability of bridging thiophenolate groups to transmit magnetic exchange interactions between paramagnetic Ni(II) ions has been examined. For this purpose, dinuclear and trinuclear Ni(II)-complexes were prepared and fully characterized by IR- and UV-vis spectroscopy, X-ray crystallography, static magnetization measurements and high-field electron spin resonance (HF-ESR). We compare structural and magnetic properties of the two Ni(II)-complexes and discuss the relationships between magnetic interactions and chemical bonding.

preprint2012arXivOpen access
Yulia KrupskayaAlexey AlfonsovAnupama ParameswaranVladislav KataevRüdiger KlingelerGunther SteinfeldNorman BeyerMathias GressenbuchBerthold KerstingBernd Büchner
cond-mat.str-el
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Open access10 authors1 topic
Imported metadata coverageMissing code, dataset, citation and institution fields are tracked without dominating the paper.Details
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Yulia KrupskayaAlexey AlfonsovAnupama ParameswaranVladislav KataevRüdiger KlingelerGunther SteinfeldNorman BeyerMathias GressenbuchBerthold KerstingBernd Büchner

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