Identities for correlation functions in classical statistical mechanics and the problem of crystal states

preprint2020arXivOpen access

Abstract

Let zz be the activity of point particles described by classical equilibrium statistical mechanics in Rν{\bf R}^ν. The correlation functions ρz(x1,…,xk)ρ^z(x_1,\dots,x_k) denote the probability densities of finding kk particles at x1,…,xkx_1,\dots,x_k. Letting ϕz(x1,…,xk)ϕ^z(x_1,\dots,x_k) be the cluster functions corresponding to the ρz(x1,…,xk)/zkρ^z(x_1,\dots,x_k)/z^k we prove identities of the type ϕz0+z′(x1,…,xk) ϕ^{z_0+z'}(x_1,\dots,x_k) =∑n=0∞z′nn!∫dxk+1 ⁣⋯∫dxk+n ϕz0(x1,…,xk+n) =\sum_{n=0}^\infty{z'^n\over n!}\int dx_{k+1}\dots\int dx_{k+n}\,ϕ^{z_0}(x_1,\dots,x_{k+n}) It is then non-rigorously argued that, assuming a suitable cluster property (decay of correlations) for a crystal state, the pressure and the translation invariant correlation functions \- ρz(x1,…,xk)ρ^z(x_1,\dots,x_k) are real analytic functions of zz.

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