Abstract
Using the molecular dynamics simulations we investigate properties of velocity autocorrelation function of Lennard-Jones fluid at long and intermediate time scales in wide ranges of temperature and density. We show that the amplitudes of the leading and subleading VAF time asymptotes, and , show essentially non monotonous temperature and density dependence. There are two lines on temperature-density plain corresponding to maxima of () along isochors and isotherms situated in the supercritical fluid (hydrodynamic anomalies). These lines give insight into the stages of the fluid evolution into gas.
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