Abstract

Using the molecular dynamics simulations we investigate properties of velocity autocorrelation function of Lennard-Jones fluid at long and intermediate time scales in wide ranges of temperature and density. We show that the amplitudes of the leading and subleading VAF time asymptotes, a1a_1 and a2a_2, show essentially non monotonous temperature and density dependence. There are two lines on temperature-density plain corresponding to maxima of a1a_1 (a2a_2) along isochors and isotherms situated in the supercritical fluid (hydrodynamic anomalies). These lines give insight into the stages of the fluid evolution into gas.

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