High-Activity Perturbation Expansion for the Hard Square Lattice Gas

preprint2012arXivOpen access

Abstract

We study a system of particles with nearest and next-nearest-neighbour exclusion on the square lattice (hard squares). This system undergoes a transition from a fluid phase at low density to a columnar ordered phase at high density. We develop a systematic high-activity perturbation expansion for the free energy per site about a state with perfect columnar order. We show that the different terms of the series can be regrouped to get a Mayer-like series for a polydisperse system of interacting vertical rods in which the nn-th term is of order z−(n+1)/2z^{-(n+1)/2}, where zz is the fugacity associated with each particle. We sum this series to get the exact expansion to order 1/z3/21/z^{3/2}.

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