Paper detail

Global existence for a hydrogen storage model with full energy balance

A thermo-mechanical model describing hydrogen storage by use of metal hydrides has been recently proposed in a paper by Bonetti, Frémond and Lexcellent. It describes the formation of hydrides using the phase transition approach. By virtue of the laws of continuum thermo-mechanics, the model leads to a phase transition problem in terms of three state variables: the temperature, the phase parameter representing the fraction of one solid phase, and the pressure, and is derived within a generalization of the principle of virtual powers proposed by Frémond accounting for micro-forces, responsible for the phase transition, in the whole energy balance of the system. Three coupled nonlinear partial differential equations combined with initial and boundary conditions have to be solved. The main difficulty in investigating the resulting system of partial differential equations relies on the presence of the squared time derivative of the order parameter in the energy balance equation. Here, the global existence of a solution to the full problem is proved by exploiting known and sharp estimates on parabolic equations with right hand side in L^1. Some complementary results on stability and steady state solutions are also given.