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Full Reaction Pathway Dynamics for Atmospheric Decomposition Reactions: The Photodissociation of H$_2$COO

Branching ratios for fragmentation channels of important meta- and unstable species are essential for a molecular-level characterization of atmospheric chemistry. Here, the molecular product channels for the decomposition dynamics of the smallest Criegee intermediate, H$_2$COO, are quantitatively investigated. Using a high-quality, full-dimensional machine learned potential energy surface (CASPT2/aug-cc-pVTZ), the translational, rotational, and vibrational energy distributions of the CO$_2$+H$_2$, H$_2$O+CO, and HCO+OH fragmentation channels were analyzed to elucidate partitioning of the available energy. The CO$_2$ + H$_2$ product forms through two different pathways that bifurcate after formation of the OCH$_2$O intermediate. Along the direct pathway, CO$_2$ is preferentially vibrationally excited with H$_2$in its vibrational ground state, whereas for the indirect pathway going through formic acid, H$_2$ can populate levels with $v > 0$. For all product channels passing through energized formic acid, the lifetime distributions are described by stretched exponentials with $β$ ranging from 1.1 to 1.7. This is a clear signature of non-RRKM effects and suggests that the explicit molecular dynamics needs to be followed for a quantitative and realistic description of the photodissociation dynamics.