Fock-space relativistic coupled-cluster calculation of hyperfine induced 1S0→3P0o\bf {^1S_0 \rightarrow {^3P^o_0}} clock transition in Al+^+

preprint2021arXivOpen access

Abstract

We have developed an all-particle Fock-space relativistic coupled-cluster method to calculate the properties of two-valence atoms and ions. Using the method we compute the properties associated with hyperfine induced 1S0−3P0o^1S_0 - ^3P^o_0 clock transition in Al+^+. Our result of the 3P0o^3P^o_0 metastable state life time, 20.20±0.9120.20 \pm 0.91 s, is in excellent agreement with the experimental value, 20.60±1.420.60 \pm 1.4 s [Phys. Rev. Lett. {\bf 98}, 220801 (2007)]. Our studies show that the contributions from the triple excitations, and the corrections from the Breit interaction and QED effects are essential to obtain accurate clock properties in Al+^+.

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