Abstract

The bands of graphite are extremely sensitive to topological defects which modify the electronic structure. In this paper we found non-dispersive flat bands no farther than 10 meV of the Fermi energy in slightly twisted bilayer graphene as a signature of a transition from a parabolic dispersion of bilayer graphene to the characteristic linear dispersion of graphene. This transition occurs for relative rotation angles of layers around 1.5o1.5^o and is related to a process of layer decoupling. We have performed ab-initio calculations to develop a tight binding model with an interaction Hamiltonian between layers that includes the ππ orbitals of all atoms and takes into account interactions up to third nearest-neighbors within a layer.

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