Finite-size effects in the quasi-one-dimensional quantum magnets Sr2_{2}CuO3_{3}, Sr2_{2}Cu0.99_{0.99}M0.01_{0.01}O3_{3} (M = Ni, Zn), and SrCuO2_{2}

preprint2015arXivOpen access

Abstract

We studied the finite-size effects on the magnetic behavior of the quasi-one-dimensional spin S = 12\frac{1}{2} Heisenberg antiferromagnets Sr2_{2}CuO3_{3}, Sr2_{2}Cu0.99_{0.99}M0.01_{0.01}O3_{3} (M = Zn and Ni), and SrCuO2_{2}. Magnetic susceptibility data were analyzed to estimate the concentration of chain-breaks due to extrinsically doped defects and/or due to slight oxygen off-stoichiometry. We show that the susceptibility of Sr2_{2}Cu0.99_{0.99}Ni0.01_{0.01}O3_{3} can be described by considering Ni2+^{2+} as a scalar defect (Seff=0S_{eff}=0) indicating that the Ni spin is screened. In Sr2_{2}Cu0.99_{0.99}Zn0.01_{0.01}O3_{3} susceptibility analysis yields a defect concentration smaller than the nominal value which is in good qualitative agreement with crystal growth experiments. Influence of doping on the low-temperature long-range spin ordered state is studied. In the compound SrCuO2_{2}, consisting of zigzag S = 12\frac{1}{2} chains, the influence of spin frustration on the magnetic ordering and the defect concentration determined from the susceptibility data is discussed.

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