Explicit Analytical Solution for Random Close Packing in d=2 and d=3

preprint2022arXivOpen access

Abstract

We present an analytical derivation of the volume fractions for random close packing (RCP) in both d=3d=3 and d=2d=2, based on the same methodology. Using suitably modified nearest neigbhour statistics for hard spheres, we obtain ϕRCP=0.65896ϕ_{\mathrm{RCP}}=0.65896 in d=3d=3 and ϕRCP=0.88648ϕ_{\mathrm{RCP}}=0.88648 in d=2d=2. These values are well within the interval of values reported in the literature using different methods (experiments and numerical simulations) and protocols. This order-agnostic derivation suggests some considerations related to the nature of RCP: (i) RCP corresponds to the onset of mechanical rigidity where the finite shear modulus emerges, (ii) the onset of mechanical rigidity marks the maximally random jammmed state and dictates ϕRCPϕ_{\mathrm{RCP}} via the coordination number zz, (iii) disordered packings with ϕ>ϕRCPϕ>ϕ_{\mathrm{RCP}} are possible at the expense of creating some order, and z=12z=12 at the FCC limit acts as a boundary condition.

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