Exceedingly Small Moment Itinerant Ferromagnetism of Single Crystalline La5_{5}Co2_{2}Ge3_{3}

preprint2020arXivOpen access

Abstract

Single crystals of monoclinic La5_{5}Co2_{2}Ge3_{3} were grown using a self-flux method and were characterized by room-temperature powder X-ray diffraction, anisotropic temperature and field dependent magnetization, temperature dependent resistivity, specific heat, and muon spin rotation. La5_{5}Co2_{2}Ge3_{3} has a Curie temperature (TCT_\mathrm{C}) of 3.8~K and clear signatures of ferromagnetism in magnetization and μSRμSR data, as well as a clear loss of spin disorder scattering in resistivity data and a sharp specific heat anomaly. The magnetism associated with La5_{5}Co2_{2}Ge3_{3} is itinerant, has a change in the entropy at TCT_\mathrm {C} of ≃\simeq0.05 R ln2 per mol-Co, and has a low-field saturated moment of ∼0.1μB\sim 0.1 μ_\mathrm B/Co, making it a rare, itinerant, small moment, low TCT_\mathrm C compound.

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