Entropy driven multi-photon frequency up-conversion

Frequency up-conversion of few low-energy photons into a single high-energy photon, greatly contributes to imaging, light sources, detection and other fields of research. However, it offers negligible efficiency when up-converting many photons. This is because coherent process are fundamentally limited due to momentum conservation requirements, while in incoherent up-conversion the finite intermediate states lifetime requires huge intensities. Thermodynamically, conventional incoherent up-conversion is driven by the internal energy of the incoming photons. However, a system can also drive work through change in its collective properties such as entropy. Here we experimentally demonstrate entropy driven ten-fold up-conversion from 10.6μ to 1μm at internal efficiency above 27% and total efficiency above 10%. In addition, the emitted radiance at 1μm exceeds the maximal possible Black-Body radiance of our device, indicating emitter's effective-temperature that is considerably above the bulk-temperature. This work opens the way for up-conversion of thermal-radiation, and high-temperature chemistry done at room-temperature.

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