Effects of c/ac/a Anisotropy and Local Crystal Structure on Superconductivity in AFe2(As1−xPx)2A\mathrm{Fe_{2}}(\mathrm{As}_{1-x}\mathrm{P}_{x}\mathrm{)_{2}} (AA=Ba1−y_{1-y}Sry_y, Sr1−y_{1-y}Cay_y and Eu)

preprint2016arXivOpen access

Abstract

We investigated the effects of c/ac/a anisotropy and local crystal structure on superconductivity (SC) in As/P solid solution systems, AFe2(As1−xPx)2A\mathrm{Fe_{2}}(\mathrm{As}_{1-x}\mathrm{P}_{x}\mathrm{)_{2}} (AA122P) with various AA ions. With decreasing AA site atomic size from AA=Ba to Eu, the structural anisotropy decreases, and the rate of decreasing with xx also increases. The rapid narrowing of the region of antiferromagnetic composition (xx) can be considered to be a result of this anisotropy change due mainly to the change in the Fermi surface (FS) nesting condition. By contrast, although the structural anisotropy systematically changes, the maximum TcT_{\mathrm{c}} values are almost the same in all AA122P systems except for Eu122P. These results indicate that the modification of the FS topology via the structural anisotropy does not affect SC. However local structural parameters, such as pnictogen height, are crucial for TcT_{\mathrm{c}}.

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