Dissipative work, Clausius inequality, and microscopic reversibility for open Hamiltonian systems

preprint2013arXivOpen access

Abstract

We derive a microscopic expression of the Clausius inequality for isothermal open systems within the fundamental Hamiltonian dynamics. We also show the positivity of the dissipative work, which is a path integral generalization of the so-called relative entropy for the probability functionals of time forward- and reversed- trajectories.

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