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Density Profiles of Liquid/Vapor Interfaces Away from Their Critical Point

We examine the applicability of various model profiles for the liquid/vapor interface by X-ray reflectivities on water and ethanol and their mixtures at room temperature. Analysis of the X-ray reflecivities using various density profiles shows an error-function like profile is the most adequate within experimental error. Our finding, together with recent observations from simulation studies on liquid surfaces, strongly suggest that the capillary-wave dynamics shapes the interfacial density profile in terms of the error function.

preprint2014arXivOpen access
Wei BuDoseok KimDavid Vaknin
cond-mat.soft
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Open access3 authors1 topic
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Wei BuDoseok KimDavid Vaknin

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