Crystal growth by Bridgman and Czochralski method of the ferromagnetic quantum critical material YbNi4_4P2_2

preprint2016arXivOpen access

Abstract

The tetragonal YbNi4_4P2_2 is one of the rare examples of compounds that allow the investigation of a ferromagnetic quantum critical point. We report in detail on two different methods which have been used to grow YbNi4_4P2_2 single crystals from a self-flux. The first, a modified Bridgman method, using a closed crucible system yields needle-shaped single crystals oriented along the [001][001]-direction. The second method, the Czochralski growth from a levitating melt, yields large single crystals which can be cut in any desired orientation. With this crucible-free method, samples without flux inclusions and a resistivity ratio at 1.8 K of RR1.8K=17_{1.8\rm K}= 17 have been grown.

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