Paper detail

Controlling Factors of Tc-Dome Structure in 1111-Type Iron Arsenide Superconductors

We investigated the effects of phosphorus substitution on the shape of the Tc(x) dome in 1111-type SmFeAs1-yPyO1-xHx (0 < x < 0.5). Hydride ion substitution of oxide sites (O2- -> H-) exerts a chemical pressure effect, i.e., a structural reduction of the Pn-Fe-Pn angle α (Pn = P, As) and also dopes electrons into the FePn layer to induce superconductivity. Isovalent phosphorus substitution (P3- -> As3-) can induce only a chemical pressure effect, i.e., an increase of α for La-substitution of Sm-sites. As y increases from 0.0 to 0.5, the single Tc dome gradually splits into two domes, similar to those of LaFeAsO1-xHx with a Tc valley at x ~ 0.16. We found that the Tc valley is located around (x, α) ~ (0.16, 113°) for both SmFeAs1-yPyO1-xHx and LaFeAsO1-xHx series, irrespective of changes in the Pn anion and Ln cation species. This result suggests that suppression of Tc leads to the emergence of a Tc valley when both the shape of FePn4 tetrahedra represented by α and electron doping level of x meet the above criterion in 1111 type iron oxypnictide superconductors.