Computational investigation of static multipole polarizabilities and sum rules for ground-state hydrogen-like ions

preprint2012arXivOpen access

Abstract

High precision multipole polarizabilities, αℓα_{\ell} for ℓ≤4\ell \le 4 of the 1s1s ground state of the hydrogen isoelectronic series are obtained from the Dirac equation using the B-spline method with Notre Dame boundary conditions. Compact analytic expressions for the polarizabilities as a function of ZZ with a relative accuracy of 10−6^{-6} up to Z=100Z = 100 are determined by fitting to the calculated polarizabilities. The oscillator strengths satisfy the sum rules ∑if0i(ℓ)=0\sum_i f^{(\ell)}_{0i} = 0 for all multipoles from ℓ=1\ell = 1 to ℓ=4\ell = 4. The dispersion coefficients for the long-range H-H and H-He+^+ interactions are given.

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