Paper detail

Collective oscillations in driven coagulation

We present a novel form of collective oscillatory behavior in the kinetics of irreversible coagulation with a constant input of monomers and removal of large clusters. For a broad class of collision rates, this system reaches a non-equilibrium stationary state at large times and the cluster size distribution tends to a universal form characterised by a constant flux of mass through the space of cluster sizes. Universality, in this context, means that the stationary state becomes independent of the cut-off as the cut-off grows. This universality is lost, however, if the aggregation rate between large and small clusters increases sufficiently steeply as a function of cluster sizes. We identify a transition to a regime in which the stationary state vanishes as the cut-off grows. This non-universal stationary state becomes unstable, however, as the cut-off is increased and undergoes a Hopf bifurcation. After this bifurcation, the stationary kinetics are replaced by persistent and periodic collective oscillations. These oscillations carry pulses of mass through the space of cluster sizes. As a result, the average mass flux remains constant. Furthermore, universality is partially restored in the sense that the scaling of the period and amplitude of oscillation is inherited from the dynamical scaling exponents of the universal regime. The implications of this new type of long-time asymptotic behaviour for other driven non-equilibrium systems are discussed.