Abstract

The bulk band structure of Bi2_2Te3_3 has been determined by angle-resolved photoemission spectroscopy and compared to first-principles calculations. We have performed calculations using the local density approximation (LDA) of density functional theory and the one-shot GWGW approximation within the all-electron full-potential linearized augmented-plane-wave (FLAPW) formalism, fully taking into account spin-orbit coupling. Quasiparticle effects produce significant changes in the band structure of \bite~when compared to LDA. Experimental and calculated results are compared in the spectral regions where distinct differences between the LDA and GWGW results are present. Overall a superior agreement with GWGW is found, highlighting the importance of many-body effects in the band structure of this family of topological insulators.

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