Abstract

Magnetism in the insulating BaFe2_2Se3_3 was examined through susceptibility, specific heat, resistivity and neutron diffraction measurements. After formation of a short-range magnetic correlation, a long-range ordering was observed below TN∼255T_{\rm N}\sim 255 K. The transition is obscured by bulk properties. Magnetic moments (∥a\parallel a) are arranged to form a Fe4_4 ferromagnetic unit, and each Fe4_4 stacks antiferromagnetically. This block magnetism is of the third type among magnetic structures of ferrous materials. The magnetic ordering drives unusually large distortion via magnetoelastic coupling.

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