Antiferro--quadrupolar structures in UPd3_3 inferred from x-ray resonant Bragg diffraction

preprint2010arXivOpen access

Abstract

A systematic analysis of resonant x-ray Bragg diffraction data for UPd3_3, with signal enhancement at the U MIV_{IV} edge, including possible structural phase-transitions leads to a new determination of the space groups of the material in the phases between T0=7.8T_0 = 7.8 K and T+1T_{+1} = 6.9 K as P2221_1 and between T−1T_{-1} = 6.7 K and T2T_{2} = 4.4 K as space group P21_1. In addition, the quadrupolar order-parameters, <Qab><Q_{ab}>, inferred from diffraction data in the phase between T−1T_{-1} and T2T_{2}, are <Qxz><Q_{xz}> and <Qyz><Q_{yz}> at the (103) Bragg reflection, and <Qxy><Q_{xy}> at the (104) reflection.

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