Anisotropic Hc2H_{c2}, thermodynamic and transport measurements, and pressure dependence of TcT_{c} in K2_{2}Cr3_{3}As3_{3} single crystals

preprint2015arXivOpen access

Abstract

We present a detailed study of single crystalline K2_{2}Cr3_{3}As3_{3} and analyze its thermodynamic and transport properties, anisotropic Hc2(T)H_{c2}(T), and initial pressure-dependence of TcT_{c}. In zero-field, the temperature-dependent resistivity is metallic. Deviation from a linear temperature-dependence is evident below 100 K and a T3T^{3}-dependence is roughly followed from just above TcT_{c} (∼\sim10 K) to ∼\sim 40 K. Anisotropic Hc2(T)H_{c2}(T) data were measured up to 140 kOe with field applied along and perpendicular to the rod-like crystals. For the applied field perpendicular to the rod, Hc2(T)H_{c2}(T) is linear with a slope ∼\sim-70 kOe/K. For field applied along the rod, the slope is about -120 kOe/K below 70 kOe. Above 70 kOe, the magnitude of the slope decreases to ∼\sim-70 kOe/K. The electronic specific heat coefficient, γγ, just above TcT_{c}, is 73 mJ/mol K2^{2}; the Debye temperature, ΘDΘ_{D}, is 220 K. The specific heat jump at the superconducting transition ΔΔC ∼\sim 2.2 γTcγT_{c}. Finally, for hydrostatic pressures up to ∼\sim7 kbar, TcT_{c} decreases under pressure linearly at a rate of -0.034 K/kbar.

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