Abstract

We performed an angle-resolved photoemission spectroscopy study of the Ni-based superconductor SrNi2_2As2_2. Electron and hole Fermi surface pockets are observed, but their different shapes and sizes lead to very poor nesting conditions. The experimental electronic band structure of SrNi2_2As2_2 is in good agreement with first-principles calculations after a slight renormalization (by a factor 1.1), confirming the picture of Hund's exchange-dominated electronic correlations decreasing with increasing filling of the 3d3d shell in the Fe-, Co- and Ni-based compounds. These findings emphasize the importance of Hund's coupling and 3d3d-orbital filling as key tuning parameters of electronic correlations in transition metal pnictides.

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