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All magnetic field values cancelling $D_1$ line transitions of alkali metal atoms

In this work, $π$, $σ^+$ and $σ^-$ transitions between magnetic sublevels of the $D_1$ line of all alkali atoms are considered analytically. General block Hamiltonian matrices in presence of a magnetic field for the ground and excited states are built in order to describe all the transitions. Eigenvalues and eigenkets describing ground and excited levels are calculated, "modified" and unperturbed transfer coefficients as a function of the nuclear spin $I$, the magnetic quantum number $m$ and the magnetic field magnitude $B$ are defined. Transition cancellations are observed only for some $π$ transitions of each isotope. The main result is that we obtain one single formula which expresses the magnetic field values cancelling these transitions. These values also correspond to the case when some of other transitions intensity have their maximum. In addition, we examine the derivative of $π$ transition "modified" transfer coefficients in order to find the magnetic field values which correspond to the intensities maximum. The accuracy of the magnetic field $B$ values is only limited by the uncertainty of the involved physical quantities.