Abstract

A new state of the H2+_2^+ molecular ion with binding energy of 1.09×10−9\times10^{-9} a.u. below the first dissociation limit is predicted, using highly accurate numerical nonrelativistic quantum calculations. It is the first L=0 excited state, antisymmetric with respect to the exchange of the two protons. It manifests itself as a huge p-H scattering length of a=750±5a=750\pm 5 Bohr radii.

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