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A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

A new organically-templated vanadium (III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling within the ground state a pronounced change in magnetisation kinetics is observed.

preprint2014arXivOpen access
Farida H. AidoudiLewis J. DownieRussell E. MorrisMark de VriesPhilip Lightfoot
cond-mat.str-el
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Farida H. AidoudiLewis J. DownieRussell E. MorrisMark de VriesPhilip Lightfoot

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