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We investigate states on von Neumann algebras which are not normal but enjoy various forms of infinite additivity, and show that these exist on $B(H)$ if and only if the cardinality of an orthonormal basis of $H$ satisfies various large cardinal conditions. For instance, there is a singular countably additive pure state on $B(l^2(κ))$ if and only if $κ$ is Ulam measurable, and there is a singular ${<}\,κ$-additive pure state on $B(l^2(κ))$ if and only if $κ$ is measurable. The proofs make use of Farah and Weaver's theory of quantum filters. Applications to Ueda's peak set theorem for von Neumann algebras are discussed in the final section.
preprint / 2016