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Wanli Yang

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Published work

10 published item(s)

preprint2026arXiv

Beyond Reasoning: Reinforcement Learning Unlocks Parametric Knowledge in LLMs

Reinforcement learning (RL) has achieved remarkable success in LLM reasoning, but whether it can also improve direct recall of parametric knowledge remains an open question. We study this question in a controlled zero-shot, one-hop, closed-book QA setting with no chain-of-thought, training only on binary correctness rewards and applying fact-level train-test deduplication to ensure gains reflect improved recall rather than reasoning or memorization. Across three model families and multiple factual QA benchmarks, RL yields ~27% average relative gains, surpassing both training- and inference-time baselines alike. Mechanistically, RL primarily redistributes probability mass over existing knowledge rather than acquiring new facts, moving correct answers from the low-probability tail into reliable greedy generations. Our data-attribution study reveals that the hardest examples are the most informative: those whose answers never appear in 128 pre-RL samples (only ~18% of training data) drive ~83% of the gain, since rare correct rollouts still emerge during training and get reinforced. Together, these findings broaden the role of RL beyond reasoning, repositioning it as a tool for unlocking rather than acquiring latent parametric knowledge.

preprint2020arXiv

Disparate exciton-phonon couplings for zone center and boundary phonons in solid-state graphite

The exciton-phonon coupling in highly oriented pyrolytic graphite is studied using resonant inelastic X-ray scattering (RIXS) spectroscopy. With ~ 70 meV energy resolution, multiple low energy excitations associated with coupling to phonons can be clearly resolved in RIXS spectra. Using resonance dependence and the closed form for RIXS cross-section without considering the intermediate state mixing of phonon modes, the dimensionless coupling constant g is determined to be 5 and 0.4, corresponding to the coupling strength of 0.42 eV +/- 40 meV and 0.21 eV +/- 30 meV, for zone center and boundary phonons respectively. The reduced g value for zone-boundary phonon may be related to its double resonance nature.

preprint2015arXiv

Generation of stable entanglement between two cavity mirrors by squeezed-reservoir engineering

The generation of quantum entanglement of macroscopic or mesoscopic bodies in mechanical motion is generally bounded by the thermal fluctuation exerted by their environments. Here we propose a scheme to establish stationary entanglement between two mechanically oscillating mirrors of a cavity. It is revealed that, by applying a broadband squeezed laser acting as a squeezed-vacuum reservoir to the cavity, a stable entanglement between the mechanical mirrors can be generated. Using the adiabatic elimination and master equation methods, we analytically find that the generated entanglement is essentially determined by the squeezing of the relative momentum of the mechanical mirrors, which is transferred from the squeezed reservoir through the cavity. Numerical verification indicates that our scheme is within the present experimental state of the art of optomechanics.

preprint2014arXiv

Measurement of the spectral line shapes for orbital excitations in the Mott insulator CoO using high-resolution resonant inelastic x-ray scattering

We establish the spectral line shape of orbital excitations created by resonant inelastic X-ray scattering for the model Mott insulator CoO. Improved experimental energy resolution reveals that the line shapes are strikingly different from expectations in a first principles-based atomic multiplet model. Extended theoretical simulations are performed to identify the underlying physical origins, which include a pronounced thermal tail reminiscent of anti-Stokes scattering on the energy gain side of excitations, and an essential contribution from interatomic many-body dynamics on the energy loss side of excitations.

preprint2012arXiv

Multiplet resonance lifetimes in resonant inelastic X-ray scattering involving shallow core levels

Resonant inelastic X-ray scattering (RIXS) spectra of model copper- and nickel-based transition metal oxides are measured over a wide range of energies near the M-edge (h$ν$=60-80eV) to better understand the properties of resonant scattering involving shallow core levels. Standard multiplet RIXS calculations are found to deviate significantly from the observed spectra. However, by incorporating the self consistently calculated decay lifetime for each intermediate resonance state within a given resonance edge, we obtain dramatically improved agreement between data and theory. Our results suggest that these textured lifetime corrections can enable a quantitative correspondence between first principles predictions and RIXS data on model multiplet systems. This accurate model is also used to analyze resonant elastic scattering, which displays the elastic Fano effect and provides a rough upper bound for the core hole shake-up response time.

preprint2012arXiv

No spin-localization phase transition in the spin-boson model without local field

We explore the spin-boson model in a special case, i.e., with zero local field. In contrast to previous studies, we find no possibility for quantum phase transition (QPT) happening between the localized and delocalized phases, and the behavior of the model can be fully characterized by the even or odd parity as well as the parity breaking, instead of the QPT, owned by the ground state of the system. Our analytical treatment about the eigensolution of the ground state of the model presents for the first time a rigorous proof of no-degeneracy for the ground state of the model, which is independent of the bath type, the degrees of freedom of the bath and the calculation precision. We argue that the QPT mentioned previously appears due to unreasonable treatment of the ground state of the model or of the infrared divergence existing in the spectral functions for Ohmic and sub-Ohmic dissipations.

preprint2012arXiv

Parity breaking and scaling behavior in the spin-boson model

We study the breaking of parity in the spin-boson model and demonstrate unique scaling behavior of the magnetization and entanglement around the critical points for the parity breaking after suppressing the infrared divergence existing inherently in the spectral functions for Ohmic and sub-Ohmic dissipations. Our treatment is basically analytical and of generality for all types of the bath. We argue that the conventionally employed spectral function is not fully reasonable and the previous justification of quantum phase transition for localization needs to be more seriously reexamined.

preprint2012arXiv

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides

We performed a systematic study of soft X-ray absorption spectroscopy in various manganese oxides and fluorides. Both Mn L-edges and ligand (O and F) K-edges are presented and compared with each other. Despite the distinct crystal structure and covalent/ionic nature in different systems, the Mn-L spectra fingerprint the Mn valence and spin states through spectral lineshape and energy position consistently and evidently. The clear O- and F- K pre-edge features in our high resolution spectra enable a quantitative definition of the molecular orbital diagram with different Mn valence. In addition, while the binding energy difference of the O-1s core electrons leads to a small shift of the O-K leading edges between trivalent and quadrivalent manganese oxides, a significant edge shift, with an order of magnitude larger in energy, was found between divalent and trivalent compounds, which is attributed to the spin exchange stabilization of half- filled 3d system. This shift is much enhanced in the ionic fluoride system. This work provides the spectroscopic foundation for further studies of complicated Mn compounds.

preprint2011arXiv

Comparison of different measures for quantum discord under non-Markovian noise

Two geometric measures for quantum discord were recently proposed by Modi et al. [Phys. Rev. Lett. 104, 080501 (2010)] and Dakic et al. [Phys. Rev. Lett. 105, 190502 (2010)]. We study the similarities and differences for total quantum correlations of Bell-diagonal states using these two geometry-based quantum discord and the original quantum discord. We show that, under non-Markovian dephasing channels, quantum discord and one of the geometric measures stay constant for a finite amount of time, but not the other geometric measure. However, all the three measures share a common sudden change point. Our study on critical point of sudden transition might be useful for keeping long time total quantum correlations under decoherence.

preprint2011arXiv

Parity-relevant Zitterbewegung and quantum simulation by a single trapped ion

Zitterbewegung (ZB), the trembling of free relativistic electrons in a vacuum could be simulated by a single trapped ion. We focus on the variations of ZB under different parity conditions and find no ZB in the case of odd or even parity. ZB occurs only for admixture of the odd and even parity states. We also show the similar role played by the parity operator for the trapped ion in Fock-state representation and the space inversion operator for a realistic relativistic electron. Although the ZB effect is invisible in a relativistic electron, preparation of the trapped ion in different parity states is a sophisticated job, which makes it possible to observe the parity relevant ZB effects with currently available techniques.