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Bo Zou

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Published work

12 published item(s)

preprint2026arXiv

Calibrated Surprise: An Information-Theoretic Account of Creative Quality

The essence of good creative writing is calibrated surprise: when constraints from all relevant dimensions act together, the feasible solution space collapses into a narrow region, and the surviving choices look least predictable from an unconstrained view. "Calibrated" has a precise meaning: the author's intent, the reader's reasonable expectation, and the logic of reality converge. When these three independent judgements agree on every dimension, the set of admissible writing choices is forced into a very small region. A mathematical corollary follows: full-dimensional accuracy and mediocrity are mutually exclusive -- two sides of one constraint structure, not separate goals. We use Shannon's mutual information $I(X;Y) = H(X) - H(X|Y)$ as our analysis tool. "Calibrated" corresponds to conditional entropy going to zero; "surprise" to entropy going up; mutual information is the precise measure of the joint quantity. The argument rests on two pillars. Static: when constraints from ethos, mythos, lexis, and dianoia are imposed together, the admissible set collapses sharply, and surviving solutions show up as low-probability choices from an unconstrained view. Dynamic: the chain rule shows each writing choice is constrained by what came before and constrains what comes after; macro-level decisions naturally contribute a larger share of information, removing the need for hand-tuned weighting. Through case studies and lightweight LLM-logprob computations, we show the framework is both analytically useful and operational, laying the theoretical groundwork for Creative Quality Alignment (CQA) and a professional evaluation benchmark.

preprint2026arXiv

Transforming Acidic Corrosion and Embrittlement into a Hydrogen-Trapping Cage

The vision of a hydrogen economy demands efficient platforms to close the gap between sustainable proton sources and solid-state hydrogen carriers. Metal hydrides serve as key carriers, yet their synthesis remains constrained by the energy-intensive use of high-pressure H2, which fragments the hydrogen chain. Here, we overturn this paradigm by transforming two classic degradation mechanisms, acidic corrosion and hydrogen embrittlement, into a constructive materials-design strategy. We demonstrate that synergistic control of these processes in acid enables the in-situ engineering of a "hydrogen-trapping cage" (HTC) microstructure within metals. Composed of a dense defect network, this cage directly captures and stabilizes protons as hydrides under mild conditions, guided by the universal criterion |DeltaPeq| > DeltaPph. Using this platform, we synthesize over 20 hydrides, including challenging targets such as LiH and NaH, and showcase its functional power with a cage-rich titanium hydride electrocatalyst. This catalyst achieves an exceptional current density of 1.07 A cm-2 for nitrate-to-ammonia conversion, attributed to rapid H- transport within the engineered cage. This work establishes a transformative "failure-to-function" paradigm, delivering an integrated platform that unifies hydrogen capture, stabilization, and conversion.

preprint2022arXiv

Reliable and Broad-range Layer Identification of Au-assisted Exfoliated Large Area MoS$_2$ and WS$_2$ Using Reflection Spectroscopic Fingerprints

The emerging Au-assisted exfoliation technique provides a wealth of large-area and high-quality ultrathin two-dimensional (2D) materials compared with traditional tape-based exfoliation. Fast, damage-free, and reliable determination of the layer number of such 2D films is essential to study layer-dependent physics and promote device applications. Here, an optical method has been developed for simple, high throughput, and accurate determination of the layer number for Au-assisted exfoliated MoS$_2$ and WS$_2$ films in a broad thickness range. The method is based on quantitative analysis of layer-dependent white light reflection spectra, revealing that the reflection peak intensity can be used as a clear indicator for determining the layer number. The simple yet robust method will facilitate the fundamental study on layer-dependent optical, electrical, and thermal properties and device applications of 2D materials. The technique can also be readily combined with photoluminescence and Raman spectroscopies to study other layer-dependent physical properties of 2D materials.

preprint2021arXiv

Critical magnetic fields and electron-pairing in magic-angle twisted bilayer graphene

The velocities of the quasiparticles that form Cooper pairs in a superconductor are revealed by the upper critical magnetic field. Here we use this property to assess superconductivity in magic-angle twisted bilayer graphene (MATBG), which has been observed over a range of moiré band filling, twist angle, and screening environment conditions. We find that for pairing mechanisms that are unrelated to correlations within the MATBG flat bands, minima in an average Fermi velocity $v_F^* \equiv k_B T_c \ell_c /\hbar $, where $\ell_c$ is the magnetic length at the critical perpendicular magnetic field, are always coincident with transition temperature maxima. Both extrema occur near flat-band van Hove singularities. Since no such association is present in MATBG experimental data, we conclude that electronic correlations that yield a band-filling-dependent pairing glue must play a crucial role in MATBG superconductivity.

preprint2021arXiv

Modeling Household Online Shopping Demand in the U.S.: A Machine Learning Approach and Comparative Investigation between 2009 and 2017

Despite the rapid growth of online shopping and research interest in the relationship between online and in-store shopping, national-level modeling and investigation of the demand for online shopping with a prediction focus remain limited in the literature. This paper differs from prior work and leverages two recent releases of the U.S. National Household Travel Survey (NHTS) data for 2009 and 2017 to develop machine learning (ML) models, specifically gradient boosting machine (GBM), for predicting household-level online shopping purchases. The NHTS data allow for not only conducting nationwide investigation but also at the level of households, which is more appropriate than at the individual level given the connected consumption and shopping needs of members in a household. We follow a systematic procedure for model development including employing Recursive Feature Elimination algorithm to select input variables (features) in order to reduce the risk of model overfitting and increase model explainability. Extensive post-modeling investigation is conducted in a comparative manner between 2009 and 2017, including quantifying the importance of each input variable in predicting online shopping demand, and characterizing value-dependent relationships between demand and the input variables. In doing so, two latest advances in machine learning techniques, namely Shapley value-based feature importance and Accumulated Local Effects plots, are adopted to overcome inherent drawbacks of the popular techniques in current ML modeling. The modeling and investigation are performed both at the national level and for three of the largest cities (New York, Los Angeles, and Houston). The models developed and insights gained can be used for online shopping-related freight demand generation and may also be considered for evaluating the potential impact of relevant policies on online shopping demand.

preprint2020arXiv

How Fast You Can Actually Fly: A Comparative Investigation of Flight Airborne Time in China and the U.S

Actual airborne time (AAT) is the time between wheels-off and wheels-on of a flight. Understanding the behavior of AAT is increasingly important given the ever growing demand for air travel and flight delays becoming more rampant. As no research on AAT exists, this paper performs the first empirical analysis of AAT behavior, comparatively for the U.S. and China. The focus is on how AAT is affected by scheduled block time (SBT), origin-destination (OD) distance, and the possible pressure to reduce AAT from other parts of flight operations. Multiple econometric models are developed. The estimation results show that in both countries AAT is highly correlated with SBT and OD distance. Flights in the U.S. are faster than in China. On the other hand, facing ground delay prior to takeoff, a flight has limited capability to speed up. The pressure from short turnaround time after landing to reduce AAT is immaterial. Sensitivity analysis of AAT to flight length and aircraft utilization is further conducted. Given the more abundant airspace, flexible routing networks, and efficient ATFM procedures, a counterfactual that the AAT behavior in the U.S. were adopted in China is examined. We find that by doing so significant efficiency gains could be achieved in the Chinese air traffic system. On average, 11.8 minutes of AAT per flight would be saved, coming from both reduction in SBT and reduction in AAT relative to the new SBT. Systemwide fuel saving would amount to over 300 million gallons with direct airline operating cost saving of nearly $1.3 billion nationwide in 2016.

preprint2015arXiv

Pressure-induced reversible phase transition and amorphization of CH$_3$NH$_3$PbI$_3$

Recent advances of highly efficient solar cells based on organic-inorganic halide perovskites have triggered intense research efforts to establish the fundamental properties of these materials. In this work, we utilized diamond anvil cell to investigate the pressure-induced structural and electronic transformations in methylammonium lead iodide (CH$_3$NH$_3$PbI$_3$) up to 7 GPa at room temperature. The synchrotron X-ray diffraction experiment show that the sample transformed from tetragonal to orthorhombic phase at 0.3 GPa and amorphized above 4 GPa. Further high pressure IR spectroscopy experiments illustrated the high pressure behavior of organic (CH$_3$NH$_3$)$^+$ cations. We also analyzed the pressure dependence of the band gap energy based on the optical absorption and photoluminescence (PL) results. Moreover, all the observed changes were fully reversible when the pressure was completely released. Our in situ high pressure studies provide essential information for the intrinsic properties and stability of organic-inorganic halide perovskites, which significantly affect the performance of perovskite solar cells.

preprint2013arXiv

Mechano-freezing of the ambient water

Raman spectroscopy examination of the 25 deg-C water freezing under compression revealed transition from 1.35 GPa to 0.86 GPa upon ice being formed at continued volume change. The transition is associated with a slight blue shift of the high-frequency phonon (omiga_H ~ 3120 cm-1) and creation of the low-frequency phonons (Omiga_L ~ 200 cm-1). In the liquid and in the solid phase, the increased pressure softens the Omiga_H and stiffens the Omida_L, which indicates the presence of the inter-electron-pair repulsion in both liquid and solid water.

preprint2013arXiv

The study of high pressure structural stability of CeO2 nanoparticles

In situ high pressure XRD diffraction and Raman spectroscopy have been performed on 12 nm CeO2 nanoparticles. Surprisingly, under quasihydrostatic condition, 12 nm CeO2 nanoparticles maintain the fluorite-type structure in the whole pressure range (0-51 GPa) during the experiments, much more stable than the bulk counterpart (PT=31 GPa). In contrast, they experienced phase transition at pressure as low as 26 GPa under non-hydrostatic condition (adopting CsCl as pressure medium). Additionally, 32-36 nm CeO2 nanoparticles exhibit an onset pressure of phase transition at 35GPa under quasihydrostatic condition, and this onset pressure is much lower than our result. Further analysis shows both the experimental condition (i.e., quasihydrostatic or non-hydrostatic) and grain size effect have a significant impact on the high pressure behaviors of CeO2 nanomaterials.

preprint2012arXiv

Ethylene glycol-mediated synthesis of nanoporous anatase TiO2 rods and rutile TiO2 self-assembly chrysanthemums

Nanoporous anatase TiO2 rods and rutile TiO2 chrysanthemums were successfully synthesized via a simple ethylene glycol-mediated synthesis route. Their morphologies, phase compositions and components were characterized by SEM, TEM, Raman and IR, respectively. The results show that a self-assembly growth takes place in the calcination under vacuum, which makes the titanium glycolate rods transform into rutile TiO2/C chrysanthemums rather than anatase TiO2 rods. It also indicates that the carbon plays an important role in the phase transition process which promotes the phase transition to rutile TiO2 at a lower temperature (400 oC). It provides a new approach to prepare nanoporous rutile TiO2 nanomaterials under low temperature.

preprint2012arXiv

Pressure-induced amorphization and polyamorphism in one-dimensional single crystal TiO2 nanomaterials

The structural phase transitions of single crystal TiO2-B nanoribbons were investigated in-situ at high-pressure using the synchrotron X-ray diffraction and the Raman scattering. Our results have shown a pressure-induced amorphization (PIA) occurred in TiO2-B nanoribbons upon compression, resulting in a high density amorphous (HDA) form related to the baddeleyite structure. Upon decompression, the HDA form transforms to a low density amorphous (LDA) form while the samples still maintain their pristine nanoribbon shape. HRTEM imaging reveals that the LDA phase has an α-PbO2 structure with short range order. We propose a homogeneous nucleation mechanism to explain the pressure-induced amorphous phase transitions in the TiO2-B nanoribbons. Our study demonstrates for the first time that PIA and polyamorphism occurred in the one-dimensional (1D) TiO2 nanomaterials and provides a new method for preparing 1D amorphous nanomaterials from crystalline nanomaterials.

preprint2010arXiv

Physical origin of superconductivity in EuFe2As1.4P0.6 and EuFe2As2: pressure-induce valence change of europium

Superconductivity can be realized in Eu-containing pnictides by application of chemical (internal) and physical (external) pressure, the intrinsic physical mechanism of which attracts much attention in physics community. Here we present the experimental evidence for the valence change of europium in compounds of EuFe2As1.4P0.6 exposed to ambient pressure and EuFe2As2 to high pressure by x-ray absorption measurements on L3-Eu edge. We find that the absorption spectrum of EuFe2As1.4P0.6 at ambient pressure shows clear spectra weight transfer from a divalent to a trivalent state. Furthermore, application of pressure on EuFe2As2 using a diamond anvil cell shows a similar behavior of valence transition as EuFe2As1.4P0.6. These findings are the first observation of superconductivity mechanized by valence change in pnictides superconductors and elucidate the intrinsic physical origin of superconductivity in EuFe2As1.4P0.6 and compressed EuFe2As2.