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Upper Bound to the Ionization Energy of 85Rb2

We report an upper bound to the ionization energy of 85Rb2 of 31348.0(6) cm-1, which also provides a lower bound to the dissociation energy D0 of 85Rb2+ of 6307.5(6) cm-1. These bounds were measured by the onset of autoionization of excited states of 85Rb2 below the 5s+7p atomic limit. We form 85Rb2 molecules via photoassociation of ultracold 85Rb atoms, and subsequently excite the molecules by single-photon ultraviolet transitions to states above the ionization threshold.

preprint2012arXivOpen access
M. A. BellosR. CarolloJ. BanerjeeM. AscoliA. -R. AlloucheE. E. EylerP. L. GouldW. C. Stwalley
physics.atom-phphysics.chem-ph
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M. A. BellosR. CarolloJ. BanerjeeM. AscoliA. -R. AlloucheE. E. EylerP. L. GouldW. C. Stwalley

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