Universal Jamming Phase Diagram in the Hard-Sphere Limit

preprint2010arXivOpen access

Abstract

We present a new formulation of the jamming phase diagram for a class of glass-forming fluids consisting of spheres interacting via finite-ranged repulsions at temperature TT, packing fraction ϕϕ or pressure pp, and applied shear stress ΣΣ. We argue that the natural choice of axes for the phase diagram are the dimensionless quantities T/pσ3T/pσ^3, pσ3/εpσ^3/ε, and Σ/pΣ/p, where TT is the temperature, pp is the pressure, ΣΣ is the stress, σσ is the sphere diameter, εε is the interaction energy scale, and mm is the sphere mass. We demonstrate that the phase diagram is universal at low pσ3/εpσ^3/ε; at low pressure, observables such as the relaxation time are insensitive to details of the interaction potential and collapse onto the values for hard spheres, provided the observables are non-dimensionalized by the pressure. We determine the shape of the jamming surface in the jamming phase diagram, organize previous results in relation to the jamming phase diagram, and discuss the significance of various limits.

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