Undulated Bilayer Interfaces in the Planar Functionalized Cahn-Hilliard Equation

preprint2022arXivOpen access

Abstract

Experiments with diblock co-polymer melts display undulated bilayers that emanate from defects such as triple junctions and endcaps, \cite{batesjain_2004}. Undulated bilayers are characterized by oscillatory perturbations of the bilayer width, which decay on a spatial length scale that is long compared to the bilayer width. We mimic defects within the functionalized Cahn-Hillard free energy by introducing spatially localized inhomogeneities within its parameters. For length parameter ε≪1\varepsilon\ll1, we show that this induces undulated bilayer solutions whose width perturbations decay on an O ⁣(ε−1/2)O\!\left(\varepsilon^{-1/2}\right) inner length scale that is long in comparison to the O(1)O(1) scale that characterizes the bilayer width.

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