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Tunneling conduction in graphene/(poly)vinyl alcohol composites

Graphene/(Poly)vinyl alcohol (PVA) composite film with thickness $60 μm$ were synthesized by solidification of a PVA solution comprising of dispersed graphene nanosheets. The close proximity of the graphene sheets enables the fluctuation induced tunneling of electrons to occur from one sheet to another. The dielectric data show that the present system can be simulated to a parallel resistance-capacitor network. The high frequency exponent of the frequency variation of the ac conductivity indicates that the charge carriers move in a two-dimensional space. The sample preparation technique will be helpful for synthesizing flexible conductors.

preprint2012arXivOpen access
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