Paper detail

Trial of a search for a face-centered-cubic high-entropy alloy superconductor

With the aim of the discovery of face-centered-cubic (fcc) high-entropy alloy (HEA) superconductor, we have carried out materials research on Nb or Pb-containing multi-component alloys. Although the X-ray diffraction (XRD) patterns of some Nb-containing samples exhibited the dominant fcc phases, no superconducting signals were observed down to 3 K. Examination with an energy dispersive X-ray spectrometer revealed that all samples were multi-phase, but the existence of several new Nb-containing HEA phases was found in them. It was confirmed that the synthesis of Pb-containing an HEA or quaternary alloy would be difficult, probably due to the large differences in the crystal structure and atomic radius among constituent elements, low reaction temperature and the lack of a rapid cooling process in the synthesis. Despite the negative results in this research, some hints for an improved strategy for the search for an fcc HEA superconductor are provided. Moreover, our results are useful as fundamental data for future HEA predictions or for studies of phase relations in Nb or Pb-containing multi-component alloys based on the CALPHAD (calculation of phase diagram) method.