Three-photon-annihilation contributions to positronium energies at order mα7m α^7

preprint2015arXivOpen access

Abstract

Positronium spectroscopy (n=1 hyperfine splitting, n=2 fine structure, and the 1S-2S interval) has reached a precision of order 1 MHz. Vigorous ongoing efforts to improve the experimental results motivate the calculation of the positronium energy levels at order mα7m α^7. In this work we present the result for a complete class of such contributions--those involving virtual annihilation of positronium to three photons in an intermediate state. We find an energy shift of 2.6216(11)mα7/(nπ)32.6216(11) m α^7/(n π)^3 for the spin-triplet S state with principal quantum number n.

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