Thermodynamic and dynamic dielectric properties of one-dimensional hydrogen bonded ferroelectric of PbHPO4_4-type

preprint2015arXivOpen access

Abstract

Within the modified model of proton ordering of one-dimensional ferroelectric having hydrogen bonds of PbHPO4_4-type, their thermodynamic and dynamic characteristics are studied and calculated taking into account the linear (by crystal deformations εi\varepsilon_i (i=1,3i=1,3) and ε4\varepsilon_4) contributions into the energy of a proton system but without taking into account the tunneling in the two-particle cluster approximation. There has been obtained a good quantitative description of the temperature dependence of polarization, static dielectric permittivity, heat capacity and frequency dependence of dynamic dielectric permittivity at different temperatures for PbHPO4_4 and PbHDO4_4 crystals.

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