Thermal Equilibrium Distribution in Infinite-Dimensional Hilbert Spaces

preprint2020arXivOpen access

Abstract

The thermal equilibrium distribution over quantum-mechanical wave functions is a so-called Gaussian adjusted projected (GAP) measure, GAP(ρβ)GAP(ρ_β), for a thermal density operator ρβρ_β at inverse temperature ββ. More generally, GAP(ρ)GAP(ρ) is a probability measure on the unit sphere in Hilbert space for any density operator ρρ (i.e., a positive operator with trace 1). In this note, we collect the mathematical details concerning the rigorous definition of GAP(ρ)GAP(ρ) in infinite-dimensional separable Hilbert spaces. Its existence and uniqueness follows from Prohorov's theorem on the existence and uniqueness of Gaussian measures in Hilbert spaces with given mean and covariance. We also give an alternative existence proof. Finally, we give a proof that GAP(ρ)GAP(ρ) depends continuously on ρρ in the sense that convergence of ρρ in the trace norm implies weak convergence of GAP(ρ)GAP(ρ).

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