Abstract
An eigenvalue of a graph is called a main eigenvalue if it has an eigenvector the sum of whose entries is not equal to zero. It is well known that a graph has exactly two main eigenvalues if and only if there exists a unique pair of integers and such that for every vertex . We collect such connected graph in the set . In this paper, we mainly focus to the existence of such and , and give the necessary and sufficient condition for . In addition, we give the bound for the vertex degrees of and use the bound to characterize the graphs in for some feasible pairs .
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