The critical pulling force for self-avoiding walks

preprint2015arXivOpen access

Abstract

Self-avoiding walks are a simple and well-known model of long, flexible polymers in a good solvent. Polymers being pulled away from a surface by an external agent can be modelled with self-avoiding walks in a half-space, with a Boltzmann weight y=efy = e^f associated with the pulling force. This model is known to have a critical point at a certain value ycy_c of this Boltzmann weight, which is the location of a transition between the so-called free and ballistic phases. The value yc=1y_c=1 has been conjectured by several authors using numerical estimates. We provide a relatively simple proof of this result, and show that further properties of the free energy of this system can be determined by re-interpreting existing results about the two-point function of self-avoiding walks.

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