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The Cosmic Evolution of the Metallicity Distribution of Ionized Gas Traced by Lyman Limit Systems

We present the first results from our KODIAQ Z survey aimed to determine the metallicity distribution and physical properties of the z>2 partial and full Lyman limit systems (pLLSs and LLSs; 16.2<log N(HI)<19), which are probed of the interface regions between the intergalactic medium (IGM) and galaxies. We study 31 HI-selected pLLSs and LLSs at 2.3<z<3.3 observed with Keck/HIRES in absorption against background QSOs. We compare the column densities of metal-ions to HI and use photoionization models to assess the metallicity. The metallicity distribution of the pLLSs/LLSs at 2.3<z<3.3 is consistent with a unimodal distribution peaking at [X/H]=-2. The metallicity distribution of these absorbers therefore evolves markedly with z since at z<1 it is bimodal with peaks at [X/H]=-1.8 and -0.3. There is a substantial fraction (25-41%) of pLLSs/LLSs with metallicities well below those of damped Lya absorbers (DLAs) at any studied z from z<1 to z~2-4, implying reservoirs of metal-poor cool, dense gas in the IGM/galaxy interface at all z. However, the gas probed by pLLSs and LLSs is rarely pristine, with a fraction 3-18% for pLLSs/LLSs with [X/H]<-3. We find C/alpha enhancement in several pLLSs and LLSs in the metallicity range -2<[X/H]<-0.5, where C/alpha is 2-5 times larger than observed in Galactic metal-poor stars or high redshift DLAs at similar metallicities. This is likely caused by preferential ejection of carbon from metal-poor galaxies into their surroundings.