Test of the diffusing-diffusivity mechanism using near-wall colloidal dynamics

preprint2016arXivOpen access

Abstract

The diffusing-diffusivity mechanism proposed by Chubynsky and Slater [PRL 113, 098302, 2014] predicts that, in environments where the diffusivity changes gradually, the displacement distribution becomes non-Gaussian, even though the mean-squared displacement (MSD) grows linearly with time. Here, we report single-particle tracking measurements of the diffusion of colloidal spheres near a planar wall. Because the local effective diffusivity is known, we have been able to carry out the first direct test of this mechanism for diffusion in inhomogeneous media.

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