Tensorial form and matrix elements of the relativistic nuclear recoil operator

preprint2011arXivOpen access

Abstract

Within the lowest-order relativistic approximation (∼v2/c2\sim v^2/c^2) and to first order in me/Mm_e/M, the tensorial form of the relativistic corrections of the nuclear recoil Hamiltonian is derived, opening interesting perspectives for calculating isotope shifts in the multiconfiguration Dirac-Hartree-Fock framework. Their calculation is illustrated for selected Li-, B- and C-like ions. The present work underlines the fact that the relativistic corrections to the nuclear recoil are definitively necessary for getting reliable isotope shift values.

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