Temperature-driven volume transition in hydrogels: phase--coexistence and interface localization

We study volume transition phenomenon in hydrogels within the framework of Flory-Rehner thermodynamic modelling; we show that starting from different models for the Flory parameter different conclusions can be achieved, in terms of admissible coexisting equilibria of the system. In particular, with explicit reference to a one-dimensional problem we establish the ranges of both temperature and traction which allow for the coexistence of a swollen and a shrunk phase. Through consideration of an augmented Flory-Rehner free-energy, which also accounts for the gradient of volume changes, we determine the position of the interface between the coexisting phases, and capture the connection profile between them.

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