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T>0 ensemble state density functional theory revisited

A logical foundation of equilibrium state density functional theory in a Kohn-Sham type formulation is presented on the basis of Mermin's treatment of the grand canonical state. it is simpler and more satisfactory compared to the usual derivation of ground state theory, and free of remaining open points of the latter. It may in particular be relevant with respect to cases of spontaneous symmetry breaking like non-collinear magnetism and orbital order.

preprint2010arXivOpen access
Helmut Eschrig
cond-mat.othercond-mat.mtrl-sci
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Helmut Eschrig

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