Abstract

We experimentally investigate the nucleation of surface nanobubbles on PFDTS-coated silicon as a function of the specific gas dissolved in the water. In each case we restrict ourselves to equilibrium conditions (c=100c=100%, Tliquid=TsubstrateT_{liquid} = T_{substrate}). Not only is nanobubble nucleation a strong function of gas type, but there also exists an optimal system temperature of ∼35−40oC\sim 35-40\mathrm{^oC} where nucleation is maximized, which is weakly dependent on gas type. We also find that contact angle is a function of nanobubble radius of curvature for all gas types investigated. Fitting this data allows us to describe a line tension which is dependent on the type of gas, indicating that the nanobubbles are sat on top of adsorbed gas molecules. The average line tension was τ∼−0.8nNτ\sim -0.8 \mathrm{nN}.

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